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生态纺织品有毒有害化学成分检测 纺织品有害物质检测



1.常见有害测试如下:

异味
pH
甲醛含量
禁用偶氮染料(24种芳香胺)AZO
重金属(120/项,500封顶)
邻苯二甲酸酯(PVC增塑剂)
有机锡化合物
二氯甲烷可溶性物质
含油脂率
乙醇萃取物、灰分、植物性杂质、总碱不溶物含量
含氯苯酚(五氯苯酚 PCP四氯苯酚 TeCP三氯苯酚 TCP
邻苯基苯酚
总铅、总镉
致病菌注3(绿脓杆菌、金黄色葡萄球菌、溶血性链球菌)
微量异物鉴定(非认证)
纺织助剂剖析(非认证)
多氯联苯
有机氯载体
致敏染料
致癌染料
烷基酚聚氧乙烯醚(APEO)
富马酸二甲酯
全氟辛酸(PFOS)和全氟辛烷磺酸盐

2.纺织有毒有害成分检验项目大全:

测试项目 Test Items测试方法  Test methods
项目分类 Classification项目说明 Instruction
物质CAS 号CAS NO物质中文名
Chinese Name
物质英文名
English Name
测试说明 Instruction已开展
Developed
1. 甲醛  Formaldehyde50-00-0甲醛FormaldehydeA. 水萃取法
water extraction method
GB/T 2912.1
ISO 14184-1
BS/DIN EN ISO 14184-1
B.蒸气吸收法
vapour absorption method
GB/T 2912.2
ISO 14184-2
BS/DIN EN ISO 14184-2
C. 密封容器法 Sealed Jar MethodAATCC 112
D.用于成品
For product
Japanese Law 112
E.皮革 LeatherISO/TS 17226-2
GB/T 19941
F.油墨甲醛 inkGB/T 18583
G.树脂整理纺织品实验方法JIS L-1041
H.外包项目DIN EN 645/ EN 1541
DIN EN 647
EN 717-3
J.此标准暂没做AATCC 94
2.PH值
PH value
PHA. 纺织品    TextileGB/T 7573
ISO 3071
JIS L-1096
JIS L-1018
AATCC 81
B.皮革 LeatherISO 4045
3 AZO  Dyestuff 偶氮 (24种被还原物质)60 --09-34-氨基偶氮苯4-AminoazobenzeneA. 4-氨基偶氮苯 4-AminoazobenzeneGB/T 23344
92-67-14– 氨联基苯4–aminobiphenyl
92-87-5联苯胺benzidine64 LFGB B 82.02-9
95-69-24– 氯邻甲苯胺4–chloro-o-toluidine
91-59-82– 萘胺2–naphthylamineB.涤纶/聚酯材料 PolyesterGB/T 17592及附录B
97-56-3邻胺基偶氮甲苯o–aminoazotoluene
99-55-85– 硝基邻甲苯胺5–nitro-o-toluidineEN 14362-2
106-47-8对氯苯胺4–chloroaniline64 LFGB B 82.02-4
615-05-42,4–二氨基甲醚2,4–diaminoanisole
101-77-94,4ˊ–二氨基二苯甲烷4,4ˊ–diaminobiphenymethaneC. 非涤纶
Non-polyester
GB/T 17592
91-94-13,3ˊ –二氯联苯胺3,3ˊ–dichlorobenzidine
119-90-43,3ˊ –二甲氧基联苯胺3,3ˊ–dimethoxybenzidineEN 14362-1
119-93-73,3ˊ–二甲基联苯胺3,3ˊ–dimethybenzidine
838-88-03,3ˊ–二甲基- 4,4ˊ–二氨基二苯甲烷4,4ˊ–methylenedi-o-toluidine64 LFGB B 82.02-2
120-71-8邻甲酚定p –cresidineD. 皮革 LeatherGB/T 19942-2005
101-14-44,4ˊ–亚甲基-二-(2-氯苯胺)4,4ˊ–methylene-bis-
(2-chloro-aniline)
ISO 17234-1
101-80-44,4ˊ–二氨基联苯醚4,4ˊ–oxydianiline64§ LFGB B 82.02-3
139-65-14,4ˊ–二氨基二苯硫醚4,4ˊ–thiodianiline
95-53-4邻甲苯胺o–toluidine
95-80-72,4–二氨基甲苯2,4 toluylendiamineE.涤纶和非涤纶混纺 Polyester and Non-polyester Blend
同时采用此项目中B和C测试方法价格增加480rmb
137-17-72,4,5 –三甲基苯胺2,4,5–trimethylaniline
90-04-0邻甲氧基苯胺o–anisidine
95-68-12,4 –二甲基苯胺2,4 –xylidine
87-62-72,6 –二甲基苯胺2,6 –xylidine
4. 致敏染料 Allergenous Dyestuff2475-45-8分散蓝1Disperse blue 1皮革制品参考纺织品标准测试DIN 54231                            GB/T 20383
2475-46-9分散蓝3Disperse blue 3
3179-90-6分散蓝7Disperse blue 7
3860-63-7分散蓝26Disperse blue 26
12222-75-2分散蓝35Disperse blue 35
12222-97-8分散蓝102Disperse blue 102
12223-01-7分散蓝106Disperse blue 106
61951-51-7分散蓝124Disperse blue 124
23355-64-8分散棕 1Disperse Brown 1
2581-69-3分散橙1Disperse Orange 1
730-40-5分散橙3Disperse Orange 3
13301-61-6分散橙37Disperse Orange 37
分散橙76Disperse Orange 76/59
2872-52-8分散红 1Disperse Red 1
2872-48-2分散红 11Disperse Red 11
3179-89-3分散红 17Disperse Red 17
119-15-3分散黄 1Disperse Yellow 1
2832-40-8分散黄 3Disperse Yellow 3
6373-73-5分散黄 9Disperse Yellow 9
12236-29-2分散黄 39Disperse Yellow 39
54824-37-2分散黄 49Disperse Yellow 49
85136-74-9分散橙 149Disperse Orange 149
6250-23-3分散黄 23Disperse Yellow 23
5.致癌染料 Carcinogenous Dyestuff3761-53-3酸性红 26Acid Red 26皮革制品参考纺织品标准测试DIN 54231                            GB/T 20382
569-61-9碱性红 9Basic Red 9
632-99-5碱性紫 14Basic Violet 14
1937-37-7直接黑 38Direct Black 38
2602-46-2直接蓝 6Direct Blue 6
573-58-0直接红 28Direct Red 28
2475-45-8分散蓝 1Disperse Blue 1
82-28-0分散橙 11Dieperse Orange 11
2832-40-8分散黄 3Disperse Yellow 3
6.重金属含量(Extractable Metal Content)欧盟包装指令重金属四项Heavy metals for Package
7440-36-0锑 SbAntimonyISO 105 E04
7440-38-2砷 AsArsenic
钡 BaBariumDIN 38406
7440-43-9镉 CdCadmium
7440-47-3铬 CrChromiumGB17593.1 AAS测试
GB17593.2 ICP测试
GB17593.4 原子荧光测砷和汞
7439-92-1铅 PbLead
7439-97-8汞 HgMercury
7782-49-2硒 SeSelenium
7440-02-0镍 NiNickel
7440-48-4钴 CoCobalt
7440-50-8铜 CuCopper
7.镍释放量 Nickel Release7440-02-0镍 NiNickelA. 无涂层金属EN1811
B.带有涂层金属
On coated items
EN 12472/EN1811
C.Spot test
8.六价铬 Chromium (VI)18540-29-9六价铬 Cr6+Chromium (VI)A. 纺织品  TextileGB/T 17593.3
ISO 105 E04 (酸性汗液萃取)
B. 皮革 LeatherISO 17075
C.非金属材料(不含皮革)US EPA 3060A&7196 A
9.总铅
Total Lead
7439-92-1铅 PbTotal LeadA.CPSC 1303
US EPA 3052
US EPA 3050B
B.首饰CA 65
10. 镉 Cadmium7440-43-9镉 CdCadmiumBS EN 1122
11.有机锡1118-46-3一丁基锡 MBTMonobutyltinISO 17353
1002-53-5二丁基锡 DBTDibutylin
56573-85-4三丁基锡 TBTTributyltin
1461-25-2四丁基锡TeBTTetrabuyltin
668-34-8三苯基锡 TPhT/TPTTriphenyltinGB/T 20385
3091-25-6一辛基三氯化锡MOTMonooctyltin trichloride
3542-36-7二辛基二氯化锡 DOTDioctyltin dichloride
三环己基氯化锡 TCyTTricyclohexyltin chloride
三丙基氯化锡 TPrTTripropyltin chloride
56-35-9三丁基氧化锡 TBTOBis-[tri-n-butyltin]Oxide
12.含氯苯酚87-86-5五氯苯酚 PCPPentachlorophenolA 纺织品 Textile
GB/T 18414
4901-51-3四氯苯酚 TeCPTetrachlorophenolB.皮革 LeatherDIN EN ISO 17070
933-78-8三氯苯酚 TCPTrichlorophenol64 LFGB B 82.02-8
13.邻苯基酚 OPP90-43-7邻苯基酚 OPPortho-phenylphenolGB/T 20386
14.烷基酚APEOs9016-45-9壬基酚聚氧乙烯醚 NPEONonylphenol ethoxylatesLC-MS
25154-52-3壬基酚 NPNonylphenol
92046-34-9辛基酚聚氧乙烯醚             OPEOOctylphenol ethoxylates
140-66-9辛基酚 OPOctylphenol
15.农药残留Pesticide Content皮革Adidas 18项可根据标准做或直接采用仪器测试GC-MS
纺织材料Adidas 25项GB 18412 (中项目做不全)
16.邻苯二甲酸盐 Phthalates (22种)117-81-7邻苯二甲酸二(2-乙基己基)酯    DEHPDi(2-ethylhexyl)phthalateA. 此八项SPD可做
EN 14372
85-68-7邻苯二甲酸丁基苄酯 BBPbutyl benzyl phthalate
84-74-2邻苯二甲酸二丁酯  DBPDibutyl phthalate
68515-48-0邻苯二甲酸二异壬酯  DINPDiisononyl phthalateCPSC-CH-C1001-09
26761-40-0邻苯二甲酸二异癸酯 DIDPDiisodecyl phthalate
117-84-0邻苯二甲酸二正辛酯  DNOPDi-n-octyl phthalateASTM D3421
(此标准已作废)
84-69-5邻苯二甲酸二异丁酯  DIBPDiisobutyl phthalate
84-75-3邻苯二甲酸二己酯 DNHPDihexyl phthalate
131-11-3邻苯二甲酸二甲酯 DMPDimethyl phthalateB.玩具做方法同上
84-66-2邻苯二甲酸二乙酯 DEPDiethyl phthalate
84-62-8邻苯二甲酸二苯酯 DPPDiphenyl phthalate
131-16-8邻苯二甲酸二丙酯 DPRPDipropyl phthalate
84-61-7邻苯二甲酸双环己酯 DCHPDicyclohexy phthalate
84-76-4邻苯二甲酸双壬酯 DNPDinonyl phthalate
3648-21-3邻苯二甲酸二庚酯 DHPDiheptyl phthalate
27554-26-3邻苯二甲酸二异辛酯 DIOPDiisooctyl phthalate
117-82-8邻苯二甲酸甲氧基乙基酯 DMEPDimethoxyethyl phthalate
605-50-5邻苯二甲酸二异戊酯 DIPPDi-isopentyl phthalate
84777-06-0邻苯二甲酸正戊基异戊基酯n-Pentyl-isopentyl phthalate
523-31-9邻苯二甲酸二苄酯 DBzPDibenzyl phthalate
131-17-9邻苯二甲酸二丙烯酯 DAPDiallyl phthalate
131-18-0邻苯二甲酸二戊酯 DPP(DnPP)Dipentyl phthalate
17.非邻苯类两项33703-08-1己二酸二异壬酯  DINADiisononyl adipate
6422-86-2对苯二甲酸二辛酯 DBzPDioctyl terephthalate
18.全氟辛烷磺酸酰基化合物 (PFOS&PFOA)2795-39-3PFOS全氟辛基磺酸衍生物perfluorooctane sulfonatesEPA 3550  (LC MS-MS)
PFOA全氟辛酸及其盐类perfluorooctanoic acid
19. 阻燃剂 (Flame Retardants)多溴联苯      PBBsPolybrominated biphenylGC-MS/GC-NPD-MS/LC-MS
-多溴联苯醚  PBDEsPolybrominated diphenyl ethers,PBDEs
126-72-73-(2,3-二溴丙基)磷酸盐   TRISTris(2,3-dibromopropyl)phosphate
545-55-13-(氮杂环丙基)-氧化磷      TEPAOTri-aziridinyl-phosphinoxide
5412-25-92-(2,3-二溴丙基)磷酸盐    BBPBis(2,3-diabromopropyl)phosphate
79-94-7四溴双酚A  TBBP-A(TBA)Tetrabromobisphenol-A
42757-55-1四溴双酚A-双(2,3-二溴丙基醚)TBBP-BIS (DBPT)Bis (2,3-diabromopropyl)ether of TBBP-A
20. 有机氯化载体(Chlorinated Aromatics organic)95-50-1/541-73-1/106-46-7二氯苯(3种)DichlorobenzenesGC-MS
87-61-6/120-82-1/108-70-3三氯苯(3种)Trichlorobenzenes
634-66-2/364-90-2/95-94-3四氯苯(3种)Tetrachlorobenzenes
608-93-5五氯苯 (1种)Pentachlorobenzenes
118-74-1六氯苯(1种)Hexachlorobenzene
95-49-8/108-41-8/106-43-4氯甲苯(3种)Chlorotoluenes
32768-54-0/95-73-8/19398-61-9/118-69-4/95-75-0二氯甲苯(5种)Dichlorotoluenes
2077-46-5/6639-30-1三氯甲苯(2种)Trichlorotoluenes
5216-25-1四氯甲苯(1种)Tetrachlorotoluenes
877-11-2五氯甲苯(1种)Pentachlorotoluene
21.气味测试 (Sensory Verification)SNV 195 651
General
22. 多氯联苯PCB (Polychlorinated Biphenyls)1336-36-3多氯联苯Polychlorinated biphenylUS EPA 8082
DIN 38407 F02
23.多氯三联苯PCT多氯三联苯Polychlorinated terphenylsUS EPA 8082
24.多氯萘 PCN多氯萘Polychlorinated naphthalenesEPA 3540C/GC-MS
25.聚氯乙烯 PVC9002-86-2聚氯乙烯                    PVCPoly(vinyl Chloride)A.定性测试FTIR
Flame
1975/1/4聚氯乙烯单体chloroethyleneB.定量测试EPA 5021
26.氯化石蜡   chlorinated paraffins85535-84-8短链氯化石蜡 C10-C13short chain chlorinated paraffins(SCCP) with C10-C13EPA 3540C/GC-MS
中链氯化石蜡 C14-C17Medium chain chlorinated paraffins(MCCP) with C14-C17EPA 3540C/GC-MS
27. 多环芳烃PAHS(16种)50-32-8苯比(a)芘Benzo(a)pyreneEPA 3550C/GC-MS

ZEK01.2-08

EPA 8270D
83-32-9二氢苊Acenaphthyene
208-96-8Acenaphthylene
120-12-7Anthracene
56-55-3苯比(a)蒽Benz(a)anthracene
205-99-2苯比(a)荧蒽Benzo(b)fluoranthene
191-24-2苯比(g,h,i)芘Benzo(g,h,i)perylene
207-08-9苯比(k)荧蒽Benzo(k)fluoranthene
218-01-9Chrysene
53-70-3二苯比(a,h)蒽Dibenz(a,h)anthracene
206-44-0荧蒽Flruoranthene
86-73-7Fluorene
193-39-5茚并(1,2,3-cd)芘Indeno(1,2,3-cd)pyrene
91-20-3Naphthalene
1985/1/8Phenathrene
129-00-0Pyrene
28. 氟氯碳化合物 Ozone Depleting Substances臭氧消耗物 95项Ozone Depleting Substance  95itemsGC-MS
29. 挥发性物质 Volatile Organic Compounds               列出Oeko-100中VOC项目50-00-0甲醛Formaldehyde
108-88-3甲苯Toluene
100-42-5苯乙烯Styrene
100-40-3乙烯基环己烷Vinylcyclohexen
4994-16-5苯基环己烷4-Phenylcyclohexen
106-99-01,3—丁二烯1,3-Butadiene
1975/1/4氯乙烯Vinylchlorid
芳香烃aromatic hydrocarbons此两项不明确需要测试哪些物质
有机挥发物organic volatiles
30. 无卤测试(F,Cl,Br,I)IEC 61249 EN14582   JY/T020-1996 /IC
31. 富马酸二甲酯 DMF624-49-7富马酸二甲酯DMFDimethylfumarateEPA,3550C为前处理方法
EPA 8270D规定使用仪器为GC/MS
32. 二甲基甲酰胺1968/12/2N,N-二甲基甲酰胺N,N-DimethylformamideEPA5021
33. 三氯生 Triclosan3380-34-55-chloro-2-(2,4-dichlorophenoxy)phenolTriclosanEPA3550C/HPLC
34.石棉 Asbestos77536-66-4阳起石ActrinoliteIR
12172-73-5铁石棉Amosite
77536-67-5青闪石Anthrophylite
12001-29-5温石棉Chrysotile
12001-28-4青石棉Crocidolite
77536-68-6透闪石Tremolite
35. 抗氧化剂 BHT128-37-02,6-二叔丁基对甲酚EPA 8270D
36. 萘成分 Naphthalene91-20-3Naphthalene ContentEPA 8270D,GC-MSD
37. 双酚A BPA1980/5/72,2-二(4-羟基苯基)丙烷Bisphenol-ABS EN ISO 8974:2002
38.二恶英及氧(杂)茂
Dioxins and Furans
见环境组项目报价
39. 生物灭杀剂 Biocide finish
40.亚硝胺
N-Nitrosamines
62-75-9N-亚硝基二甲胺N-nitrosodimethylamine (NDMA)GB25036, GB25038
55-18-5N-亚硝基二乙胺N-nitrosodiethylamine (NDEA)
621-64-7N-亚硝基二丙基胺N-nitrosodipropylamine(NDPA)
924-16-3N-亚硝基二丁基胺N-nitrosodibutylamine (NDBA)
100-75-4N-亚硝基哌啶N-nitrosopiperidine(NPIP)
930-55-2N-亚硝基吡咯烷N-nitrosopyrrolidine (NPYR)
59-89-2N-亚硝基吗啉N-nitrosomorpholine(NMOR)
614-00-6N-亚硝基-N-甲基苯胺N-nitroso N-methyl N-phenylamine(NMPhA)
612-64-6N-亚硝基-N-乙基苯胺N-nitroso N-ethyl N-phenylamine (NEPhA)
41.苯酚PhenolISO 8974



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